Damaged the Jeoguibon (patterns of the Queen's ceremonial robe) was found during repair work of Daejojeon, Changdeok Palace in 2011. Analytical study on seven colors painted in the patterns has been conducted by P-XRF and Micro-XRD analysis. The result displays that red lead, ultramarine blue, conichalcite or mixed pigment of emerald green and barium white, orpiment and white lead had been used on the patterns. Comparison of the pigments used for the Pyeseulbon (patterns of the Queen's belt ornament covering knees in the front) housed in National Museum of Korea has revealed that not only red lead but also cinnabar and organic pigment had been used in the Jeoguibon and the Pyeseulbon housed in National Museum of Korea. In addition the same pigments has been examined in green and yellow parts of both the Jeoguibon in Daejojeon and the Pyeseulbon housed in National Museum of Korea. The result has shown that western's synthetic green pigment such as emerald green was introduced and used in 1920's. The scientific result from this study expects to be used as useful referencing data for the comparative understanding on pigments used in palace during the 20th century.