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Journal of Conservation Science Vol.23 No.0 pp.1-10

알콕시 실란계 석재 강화제의 화강암 점착 특성 연구

김은경,손승환,원종옥,김정진,김사덕

Study of Adhesion Phenomena of Alkoxysilane-type Consolidants on Fresh Granites

Eun Kyung Kim,Seunghwan Son,Jongok Won,Jeong-Jin Kim,Sa Dug Kim

Abstract

Consolidants based on tetraethoxysilane (TEOS) such as alkoxysilanes have been widely used for the consolidation of decaying stone heritages. Low-viscosity alkoxysilanes penetrate inside the decaying stone and polymerize within the porous structure of the decaying stone, significantly increasing the cohesion of the material. However, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force, which is typical for TEOS-based consolidants. We prepared new consolidants TEOS-based consolidants containing flexible (3-glycidoxypropyl)trimethoxysilane (GPTMS) and silica nanoparticles (or polyhedral oligomeric silsesquioxanes (POSS)) in order to reduce capillary force development during gel drying. Since the consolidants should have a good interaction with the component of the stone in order to connect the isolate grains of decaying stone, the adhesion interaction of the developed consolidants on the surface of the granite was macroscopically investigated by the ISO 2409 cross cutting test. The adhesion interaction decreased with the addition of silica nanoparticle and POSS while it increased with the addition of GPTMS in TEOS solution.

Vol. 40 No. 4 (2022.12)

Journal of Conservation Science Journal Abbreviation J. Conserv. Sci.
Frequency Quarterly
Doi Prefix 10.12654
Publisher The Korean Society of Conservation Science for Cultural Heritage
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